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40d:Raw adamantine
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The ore of adamantine is highly valuable. Its discovery is both a boon and a bane; it has a massive value even unrefined, and gives a large number of bonuses to armor and weapons that are made from it. The downside is that digging too deeply will trigger a certain spoiler, among other things, including the fact that it only appears in minute quantities.
Its high melting point means you can easily use it to build magma-safe mechanisms and floodgates, but this is not recommended due to its scarcity.
Finding this material will cause a notification, and for the King to appear later on. If you haven't met his requirements, he will appear dressed as a peasant. It is assumed that his requirements are the same in either case.